Protocol on Control of Volatile Organic Compounds Emissions (1991)
Determined to implement the Convention on Long-range Transboundary Air Pollution,
Concerned that present emissions of volatile organic compounds (VOCs) and the resulting secondary photochemical oxidant products are causing damage, in exposed parts of Europe and North America, to natural resources of vital environmental and economic importance and, under certain exposure conditions, have harmful effects on human health,
Noting that under the Protocol concerning the Control of Emissions of Nitrogen Oxides or their Transboundary Fluxes, adopted in Sofia on 31 October 1988, there is already agreement to reduce emissions of oxides of nitrogen,
Recognizing the contribution of VOCs and nitrogen oxides to the formation of tropospheric ozone,
Recognizing also that VOCs, nitrogen oxides and resulting ozone are transported across international boundaries, affecting air quality in neighbouring States,
Aware that the mechanism of photochemical oxidant creation is such that the reduction of emissions of VOCs is necessary in order to reduce the incidence of photochemical oxidants,
Further aware that methane and carbon monoxide emitted by human activities are present at background levels in the air over the ECE region and contribute to the formation of episodic peak ozone levels; that, in addition, their global-scale oxidation in the presence of nitrogen oxides contributes to the formation of the background levels of tropospheric ozone upon which photochemical episodes are superimposed; and that methane is expected to become the subject of control actions in other forums,
Recalling that the Executive Body for the Convention identified at its sixth session the need to control emissions of VOCs or their transboundary fluxes, as well as to control the incidence of photochemical oxidants, and the need for Parties that had already reduced these emissions to maintain and review their emission standards for VOCs,
Acknowledging the measures already taken by some Parties which have had the effect of reducing their national annual emissions of nitrogen oxides and VOCs,
Noting that some Parties have set air quality standards and/or objectives for tropospheric ozone and that standards for tropospheric ozone concentrations have been set by the World Health Organization and other competent bodies,
Determined to take effective action to control and reduce national annual emissions of VOCs or the transboundary fluxes of VOCs and the resulting secondary photochemical oxidant products, in particular by applying appropriate national or international emission standards to new mobile and new stationary sources and retrofitting existing major stationary sources, and also by limiting the content of components in products for industrial and domestic use that have the potential to emit VOCs,
Conscious that volatile organic compounds differ greatly from each other in their reactivity and in their potential to create tropospheric ozone and other photochemical oxidants and that, for any individual compounds, potential may vary from time to time and from place to place depending on meteorological and other factors,
Recognizing that such differences and variations should be taken into consideration if action to control and reduce emissions and transboundary fluxes of VOCs is to be as effective as possible in minimizing the formation of tropospheric ozone and other photochemical oxidants,
Taking into consideration existing scientific and technical data on emissions, atmospheric movements and effects on the environment of VOCs and photochemical oxidants, as well as on control technologies,
Recognizing that scientific and technical knowledge of these matters is developing and that it will be necessary to take such developments into account when reviewing the operation of the present Protocol and deciding on further action,
Noting that the elaboration of an approach based on critical levels is aimed at the establishment of an effect-oriented scientific basis to be taken into account when reviewing the operation of the present Protocol, and at deciding on further internationally agreed measures to limit and reduce emissions of VOCs or the transboundary fluxes of VOCs and photochemical oxidants,
Have agreed as follows:
Article 1 Definitions
For the purposes of the present Protocol,
1. “Convention” means the Convention on Long-range Transboundary Air Pollution, adopted in Geneva on 13 November 1979;
2. “EMEP” means the Cooperative Programme for Monitoring and Evaluation of the Long- range Transmission of Air Pollutants in Europe;
3. “Executive Body” means the Executive Body for the Convention constituted under article 10, paragraph 1, of the Convention;
4. “Geographical scope of EMEP” means the area defined in article 1, paragraph 4, of the Protocol to the 1979 Convention on Long-range Transboundary Air Pollution on Long-term Financing of the Cooperative Programme for Monitoring and Evaluation of the Long-range Transmission of Air Pollutants in Europe (EMEP), adopted in Geneva on 28 September 1984;
5. “Tropospheric ozone management area” (TOMA) means an area specified in annex I under conditions laid down in article 2, paragraph 2 (b);
6. “Parties” means, unless the context otherwise requires, the Parties to the present Protocol;
7. “Commission” means the United Nations Economic Commission for Europe;
8. “Critical levels” means concentrations of pollutants in the atmosphere for a specified exposure time below which direct adverse effects on receptors, such as human beings, plants, ecosystems or materials do not occur according to present knowledge;
9. “Volatile organic compounds”, or “VOCs”, means, unless otherwise specified, all organic compounds of anthropogenic nature, other than methane, that are capable of producing photochemical oxidants by reactions with nitrogen oxides in the presence of sunlight;
10. “Major source category” means any category of sources which emit air pollutants in the form of VOCs, including the categories described in annexes II and III, and which contribute at least 1 per cent of the total national emissions of VOCs on an annual basis, as measured or calculated in the first calendar year after the date of entry into force of the present Protocol, and every fourth year thereafter;
11. “New stationary source” means any stationary source of which the construction or substantial modification is commenced after the expiry of two years from the date of entry into force of the present Protocol;
12. “New mobile source” means any on-road motor vehicle which is manufactured after the expiry of two years from the date of entry into force of the present Protocol;
13. “Photochemical ozone creation potential” (POCP) means the potential of an individual VOC, relative to that of other VOCs, to form
ozone by reaction with oxides of nitrogen in the presence of sunlight, as described in annex IV.
1. The Parties shall control and reduce their emissions of VOCs in order to reduce their transboundary fluxes and the fluxes of the resulting secondary photochemical oxidant products so as to protect human health and the environment from adverse effects.
2. Each Party shall, in order to meet the requirements of paragraph 1 above, control and reduce its national annual emissions of VOCs or their transboundary fluxes in any one of the following ways to be specified upon signature:
(a) It shall, as soon as possible and as a first step, take effective measures to reduce its national annual emissions of VOCs by at least 30 per cent by the year 1999, using 1988 levels as a basis or any other annual level during the period 1984 to 1990, which it may specify upon signature of or accession to the present Protocol; or
(b) Where its annual emissions contribute to tropospheric ozone concentrations in areas under the jurisdiction of one or more other Parties, and such emissions originate only from areas under its jurisdiction that are specified as TOMAs in annex I, it shall, as soon as possible and as a first step, take effective measures to:
(i) Reduce its annual emissions of VOCs from the areas so specified by at least 30 per cent by the year 1999, using 1988 levels as a basis or any other annual level during the period 1984-1990, which it may specify upon signature of or accession to the present Protocol; and
(ii) Ensure that its total national annual emissions of VOCs by the year 1999 do not exceed the 1988 levels; or
(c) Where its national annual emissions of VOCs were in 1988 lower than 500,000 tonnes and 20 kg/inhabitant and 5 tonnes/km2, it shall, as soon as possible and as a first step, take effective measures to ensure at least that at the latest by the year 1999 its national annual emissions of VOCs do not exceed the 1988 levels.
3. (a) Furthermore, no later than two years after the date of entry into force of the present Protocol, each Party shall:
(i) Apply appropriate national or international emission standards to new stationary sources based on the best available technologies which are economically feasible, taking into consideration annex II;
(ii) Apply national or international measures to products that contain solvents and promote the use of products that are low in or do not contain VOCs, taking into consideration annex II, including the labelling of products specifying their VOC content;
(iii) Apply appropriate national or international emission standards to new mobile sources based on the best available technologies which are economically feasible, taking into consideration annex III; and
(iv) Foster public participation in emission control programmes through public announcements, encouraging the best use of all modes of transportation and promoting traffic management schemes.
(b) Furthermore, no later than five years after the date of entry into force of the present Protocol, in those areas in which national or international tropospheric ozone standards are exceeded or where transboundary fluxes originate or are expected to originate, each Party shall:
(i) Apply the best available technologies that are economically feasible to existing stationary sources in major source categories, taking into consideration annex II;
(ii) Apply techniques to reduce VOC emissions from petrol distribution and motor vehicle refuelling operations, and to reduce volatility of petrol, taking into consideration annexes II and III.
4. In carrying out their obligations under this article, Parties are invited to give highest priority to reduction and control of emissions of substances with the greatest POCP, taking into consideration the information contained in annex IV.
5. In implementing the present Protocol, and in particular any product substitution measures, Parties shall take appropriate steps to ensure that toxic and carcinogenic VOCs, and those that harm the stratospheric ozone layer, are not substituted for other VOCs.
6. The Parties shall, as a second step, commence negotiations, no later than six months after the date of entry into force of the present Protocol, on further steps to reduce national annual emissions of volatile organic compounds or transboundary fluxes of such emissions and their resulting secondary photochemical oxidant products, taking into account the best available scientific and technological developments, scientifically determined critical levels and internationally accepted target levels, the role of nitrogen oxides in the formation of photochemical oxidants and other elements resulting from the work programme undertaken under article 5.
7. To this end, the Parties shall cooperate in order to establish:
(a) More detailed information on the individual VOCs and their POCP values;
(b) Critical levels for photochemical oxidants;
(c) Reductions in national annual emissions or transboundary fluxes of VOCs and their resulting secondary photochemical oxidant products, especially as required to achieve agreed objectives based on critical levels;
(d) Control strategies, such as economic instruments, to obtain overall cost- effectiveness to achieve agreed objectives;
(e) Measures and a timetable commencing no later than 1 January 2000 for achieving such reductions.
8. In the course of these negotiations, the Parties shall consider whether it would be appropriate for the purposes specified in paragraph 1 to supplement such further steps with measures to reduce methane.
Article 3 Further measures
1. Measures required by the present Protocol shall not relieve Parties from their other obligations to take measures to reduce total gaseous emissions that may contribute significantly to climate change, to the formation of tropospheric background ozone or to the depletion of stratospheric ozone, or that are toxic or carcinogenic.
2. Parties may take more stringent measures than those required by the present Protocol.
3. The Parties shall establish a mechanism for monitoring compliance with the present Protocol. As a first step based on information provided pursuant to article 8 or other
information, any Party which has reason to believe that another Party is acting or has acted in a manner
inconsistent with its obligations under this Protocol may inform the Executive Body to that effect and, simultaneously, the Parties concerned. At the request of any Party, the matter may be taken up at the next meeting of the Executive Body.
Exchange of technology
1. The Parties shall, consistent with their national laws, regulations and practices, facilitate the exchange of technology to reduce emissions of VOCs, particularly through the promotion of:
(a) The commercial exchange of available technology;
(b) Direct industrial contacts and cooperation, including joint ventures;
(c) The exchange of information and experience;
(d) The provision of technical assistance.
2. In promoting the activities specified in paragraph 1 of this article, the Parties shall create favourable conditions by facilitating contacts and cooperation among appropriate organizations and individuals in the private and public sectors that are capable of providing technology, design and engineering services, equipment or finance.
3. The Parties shall, no later than six months after the date of entry into force of the present Protocol, commence consideration of procedures to create more favourable conditions for the exchange of technology to reduce emissions of VOCs.
Research and monitoring to be undertaken
The Parties shall give high priority to research and monitoring related to the development and application of methods to achieve national or international tropospheric ozone standards and other goals to protect human health and the environment. The Parties shall, in particular, through national or international research programmes, in the work-plan of the Executive Body and through other cooperative programmes within the framework of the Convention, seek to:
(a) Identify and quantify effects of emissions of VOCs, both anthropogenic and biogenic, and photochemical oxidants on human health, the environment and materials;
(b) Determine the geographical distribution of sensitive areas;
(c) Develop emission and air quality monitoring and model calculations including methodologies for the calculation of emissions, taking into account, as far as possible, the different VOC species, both anthropogenic and biogenic, and their reactivity, to quantify the long-range transport of VOCs, both
anthropogenic and biogenic, and related pollutants involved in the formation of photochemical oxidants;
(d) Improve estimates of the performance and costs of technologies for control of emissions of VOCs and record the development of improved and new technologies;
(e) Develop, within the context of the approach based on critical levels, methods to integrate scientific, technical and economic data in order to determine appropriate rational strategies for limiting VOC emissions and obtain overall cost-effectiveness to achieve agreed objectives;
(f) Improve the accuracy of inventories of emissions of VOCs, both anthropogenic and biogenic, and harmonize the methods of their calculation or estimation;
(g) Improve their understanding of the chemical processes involved in the creation of photochemical oxidants;
(h) Identify possible measures to reduce emissions of methane.
1. The Parties shall regularly review the present Protocol, taking into account the best available scientific substantiation and technological development.
2. The first review shall take place no later than one year after the date of entry into force of the present Protocol.
National programmes, policies and strategies
The Parties shall develop without undue delay national programmes, policies and strategies to implement the obligations under the present Protocol that shall serve as a means of controlling and reducing emissions of VOCs or their transboundary fluxes.
Information exchange and annual reporting
1. The Parties shall exchange information by notifying the Executive Body of the national programmes, policies and strategies that they develop in accordance with article 7, and by reporting to it progress achieved under, and any changes to, those programmes, policies and strategies. In the first year after entry into force of this Protocol, each Party shall report on the level of emissions of VOCs in its territory and any TOMA in its territory, by total and, to the extent feasible, by sector of origin and by individual VOC, according to guidelines to be specified by the Executive Body for 1988 or any other year taken as the base year for article 2.2 and on the basis upon which these levels have been calculated.
2. Furthermore each Party shall report annually:
(a) On the matters specified in paragraph 1 for the previous calendar year, and on any revision which may be necessary to the reports already made for earlier years;
(b) On progress in applying national or international emission standards and the control techniques required under article 2, paragraph 3;
(c) On measures taken to facilitate the exchange of technology.
3. In addition, Parties within the geographical scope of EMEP shall report, at intervals to be specified by the Executive Body, information on VOC emissions by sector of origin, with a spatial resolution, to be specified by the Executive Body, appropriate for purposes of modelling the formation and transport of secondary photochemical oxidant products.
4. Such information shall, as far as possible, be submitted in accordance with a uniform reporting framework.
EMEP shall, utilizing appropriate models and measurements, provide to the annual meetings of the Executive Body relevant information on the long-range transport of ozone in Europe. In areas outside the geographical scope of EMEP, models appropriate to the particular circumstances of Parties to the Convention therein shall be used.
The annexes to the present Protocol shall form an integral part of the Protocol. Annex I is mandatory while annexes II, III and IV are recommendatory.
Amendments to the Protocol
1. Any Party may propose amend
ments to the present Protocol.
2. Proposed amendments shall be submitted in writing to the Executive Secretary of the Commission, who shall communicate them to all Parties. The Executive Body shall discuss the proposed amendments at its next annual meeting, provided that those proposals have been circulated by the Executive Secretary to the Parties at least 90 days in advance.
3. Amendments to the Protocol, other than amendments to its annexes, shall be adopted by consensus of the Parties present at a meeting of the Executive Body, and shall enter into force for the Parties which have accepted them on the ninetieth day after the date on which two thirds of the Parties have deposited their instruments of acceptance thereof. Amendments
shall enter into force for any Party which has accepted them after two thirds of the Parties have deposited their instruments of acceptance of the amendment, on the ninetieth day after the date on which that Party deposited its instrument of acceptance of the amendments.
4. Amendments to the annexes shall be adopted by consensus of the Parties present at a meeting of the Executive Body and shall become effective 30 days after the date on which they have been communicated, in accordance with paragraph 5 of this article.
5. Amendments under paragraphs 3 and 4 of this article shall, as soon as possible after their adoption, be communicated by the Executive Secretary to all Parties.
Settlement of disputes
If a dispute arises between two or more Parties as to the interpretation or application of the present Protocol, they shall seek a solution by negotiation or by any other method of dispute settlement acceptable to the parties to the dispute.
1. The present Protocol shall be open for signature at Geneva from 18 November 1991 until 22 November 1991 inclusive, then at the United Nations Headquarters in New York until 22 May 1992, by the States members of the Commission as well as States having consultative status with the Commission, pursuant to paragraph 8 of Economic and Social Council resolution 36 (IV) of 28 March 1947, and by regional economic integration organizations, constituted by sovereign States members of the Commission, which have competence in respect of the negotiation, conclusion and application of international agreements in matters covered by the Protocol, provided that the states and organizations concerned are Parties to the Convention.
2. In matters within their competence, such regional economic integration organizations shall, on their own behalf, exercise the rights and fulfil the responsibilities which the present Protocol attributes to their member states. In such cases, the member states of these organizations shall not be entitled to exercise such rights individually.
Ratification, acceptance, approval and accession
1. The present Protocol shall be subject to ratification, acceptance or approval by Signatories.
2. The present Protocol shall be open for accession as from 22 May 1992 by the States and organizations referred to in article 13, paragraph 1.
The instruments of ratification, acceptance, approval or accession shall be deposited with the Secretary-General of the United Nations, who will perform the functions of Depositary.
Entry into force
1. The present Protocol shall enter into force on the ninetieth day following the date on which the sixteenth instrument of ratification, acceptance, approval or accession has been deposited.
2. For each State and organization referred to in article 13, paragraph 1, which ratifies, accepts or approves the present Protocol or accedes thereto after the deposit of the sixteenth instrument of ratification, acceptance, approval or accession, the Protocol shall enter into force on the ninetieth day following the date of deposit by such Party of its instrument of ratification, acceptance, approval or accession.
At any time after five years from the date on which the present Protocol has come into force with respect to a Party, that Party may withdraw from it by giving written notification to the Depositary. Any such withdrawal shall take effect on the ninetieth day following the date of its receipt by the Depositary, or on such later date as may be specified in the notification of the withdrawal.
Article 18 Authentic texts
The original of the present Protocol, of which the English, French and Russian texts are equally authentic, shall be deposited with the Secretary-General of the United Nations.
In witness whereof the undersigned, being duly authorized thereto, have signed the present Protocol.
Done at Geneva this eighteenth day of November one thousand nine hundred and ninety-one.
Designated tropospheric ozone management areas
The following TOMAs are specified for the purposes of this Protocol: Canada
TOMA No. 1: The Lower Fraser Valley in the Province of British Columbia.
This is a 16,800-km2 area in the southwestern corner of the Province of British Columbia averaging 80 km in width and extending 200 km up the Fraser River Valley from the mouth of the river in the Strait of Georgia to Boothroyd, British Columbia. Its southern boundary is the Canada/United States international boundary and it includes the Greater Vancouver Regional District.
TOMA No. 2: The Windsor-Quebec Corridor in the Provinces of Ontario and Quebec.
This is a 157,000-km2 area consisting of a strip of land 1,100 km long and averaging 140 km in width stretching from the City of Windsor (adjacent to Detroit in the united states) in the Province of Ontario to Quebec City in the Province of Quebec. The Windsor-Quebec Corridor TOMA is located along the north shore of the Great Lakes and the St. Lawrence River in Ontario and straddles the St. Lawrence River from the Ontario- Quebec border to Quebec City in Quebec. It includes the urban centres of Windsor, London, Hamilton, Toronto, Ottawa, Montreal, Trois-Rivieres and Quebec City.
The total Norwegian mainland as well as the exclusive economic zone south of 62°N latitude in the region of the Economic Commission for Europe (ECE), covering an area of 466,000 km2.
Control measures for emissions of volatile organic compounds
(VOCs) from stationary sources
I. MAJOR SOURCES OF VOC EMISSIONS FROM STATIONARY SOURCES
II. GENERAL OPTIONS FOR VOC-EMISSION REDUCTION
III. CONTROL TECHNIQUES"text-align: justify;">IV. SECTORS
1. The aim of this annex is to provide the Parties to the Convention with guidance in identifying best available technologies to enable them to meet the obligations of the Protocol.
2. Information regarding emission performance and costs is based on official documentation of the Executive Body and its subsidiary bodies, in particular documents received and reviewed by the Task Force on Emissions of VOCs from Stationary Sources. Unless otherwise indicated, the techniques listed are considered to be well established on the basis of operational experience.
3. Experience with new products and new plants incorporating low-emission techniques, as well as with the retrofitting of existing plants, is continuously growing; the regular elaboration and amendment of the annex will therefore be necessary. Best available technologies identified for new plants can be applied to existing plants after an adequate transition period.
4. The annex lists a number of measures spanning a range of costs and efficiencies. The choice of measures for any particular case will depend on a number of factors, including economic circumstances, technological infrastructure and any existing VOC control implemented.
5. This annex does not, in general, take into account the specific species of VOC emitted by the different sources, but deals with best available technologies for VOC reduction. When measures are planned for some sources, it is worthwhile to consider giving priority to those activities which emit reactive rather than non-reactive VOCs (e.g. in the solvent-using sector). However, when such compound-specific measures are designed, other effects on the environment (e.g. global climate change) and on human health should also be taken into account.
I. MAJOR SOURCES OF VOC EMISSIONS FROM STATIONARY SOURCES
6. The major sources of anthropogenic non-methane VOC emissions from stationary sources are the following:
(a) Use of solvents;
(b) Petroleum industry including petroleum-product handling;
(c) Organic chemical industry;
(d) Small-scale combustion sources (e.g. domestic heating and small industrial boilers);
(e) Food industry;
(f) Iron and steel industry;
(g) Handling and treatment of wastes;
7. The order of the list reflects the general importance of the sources subject to the uncertainties of emission inventories. The distribution of VOC emissions according to different sources depends greatly on the fields of activity within the territory of any particular Party.
II. GENERAL OPTIONS FOR VOC-EMISSION REDUCTION
8. There are several possibilities for the control or prevention of VOC emissions. Measures for the reduction of VOC emissions focus on products and/or process modifications (including maintenance and operational control) and on the retrofitting of existing plants. The following list gives a general outline of measures available, which may be implemented either singly or in combination:
(a) Substitution of VOCs; e.g. the use of water-based degreasing baths, and paints, inks, glues or adhesives which are low in or do not contain VOCs;
(b) Reduction by best management practices such as good housekeeping, preventive maintenance programmes, or by changes in processes such as closed systems during utilization, storage and distribution of low-boiling organic liquids;
(c) Recycling and/or recovery of efficiently collected VOCs by control techniques such as adsorption, absorption, condensation and membrane processes; ideally, organic compounds can be reused on-site;
(d) Destruction of efficiently collected VOCs by control techniques such as thermal or catalytic incineration or biological treatment.
9. The monitoring of abatement procedures is necessary to ensure that appropriate control measures and practices are properly implemented for an effective reduction of VOC emissions. Monitoring of abatement procedures will include:
(a) The development of an inventory of those VOC-emission reduction measures, identified above, that have already been implemented;
(b) The characterization and quantification of VOC emissions from relevant sources by instrumental or other techniques;
(c) Periodic auditing of abatement measures implemented to ensure their continued efficient operation;
(d) Regularly scheduled reporting on (a), (b) and (c), using harmonized procedures, to regulatory authorities;
(e) Comparison, with the objectives of the Protocol, of VOC-emission reductions achieved in practice.
10. The investment/cost figures have been collected from various sources. On account of the many influencing factors, investment/cost figures are highly case-specific. If the unit ” “cost per tonne of VOC abated” is used for cost-efficient strategy considerations, it must be borne in mind that such specific figures are highly dependent on factors such as plant capacity, removal efficiency and raw gas VOC concentration, type of technology, and the choice of new installations as opposed to retrofitting. Illustrative cost figures should also be based on process- specific parameters, e.g. mg/m2 treated (paints), kg/m3 product or kg/unit.
11. Cost-efficient strategy considerations should be based on total costs per year (including capital and operational costs). VOC-emission reduction costs should also be considered within the framework of the overall process economics, e.g. the impact of control measures and costs on the costs of production.
III. CONTROL TECHNIQUES
12. The major categories of available control techniques for VOC abatement are summarized in table 1. Those techniques chosen for inclusion in the table have been successfully applied commercially and are now well established. For the most part, they have been applied generally across sectors.
13. Sector-specific techniques, including the limitation of the solvent content of products, are given in sections IV and V.
14. Care should be taken to ensure that the implementation of these control techniques does not create other environmental problems. If incineration has to be used, it should be combined with energy recovery, where appropriate.
15. Using such techniques, concentrations of below 150 mg/m3 (as total carbon, standard
conditions) can usually be achieved in exhaust air flows. In most cases, emission values of 1050 mg/m3 can be achieved.
16. Another common procedure for destroying non-halogenated VOCs is to use VOC-laden gas streams as secondary air or fuel in existing energy-conversion units. However, this usually requires site-specific process modifications and therefore it too is excluded from the following table.
17. Data on efficiency are derived from operational experience and are considered to reflect the capabilities of current installations.
18. Cost data are more subject to uncertainty due to interpretation of costs, accountancy practices and site-specific conditions. Therefore the data provided are case-specific. They cover the cost ranges for the different techniques. The costs do, however, accurately reflect the relationships between the costs of the different techniques. Differences in costs between new and retrofit applications may in some cases be significant but do not differ sufficiently to change the order in table 1.
19. The choice of a control technique will depend on parameters such as the concentration of VOCs in the raw gas, gas volume flow, the type of VOCs, and others. Therefore, some overlap in the fields of application may occur; in that case, the most appropriate technique must be selected according to case-specific conditions.
20. In this section, each VOC-emitting sector is characterized by a table containing the main emission sources, control measures including the best available technologies, their specific reduction efficiency and the related costs.
21. An estimate is also provided of the overall potential within each sector for reducing its VOC emissions. The maximum reduction potential refers to situations in which only a low level of control is in place.
22. Process-specific reduction efficiencies should not be confused with the figures given for the reduction potential of each sector. The former are technical feasibilities, while the latter take into account the likely penetration and other factors affecting each sector. The process- specific efficiencies are given only qualitatively, as follows:
I = > 95%; II = 80-95%; III = < 80%
23. Costs depend on capacity, site-specific factors, accountancy practices and other factors. Consequently, costs may vary greatly; therefore, only qualitative information (medium, low, high) is provided, referring to comparisons of costs of different technologies mentioned for specific applications.
A. Industrial use of solvents
24. The industrial use of solvents is in many countries the biggest contributor to VOC emissions from stationary sources. Main sectors and control measures, including best available technologies and reduction efficiencies, are listed in table 2, and the best available technology is specified for each sector. There may be differences between small and large or new and old plants. For this reason, the estimated overall reduction potential quoted is below the values implied in table 2.
The estimated overall reduction potential for this sector is up to 60 per cent. A further step to reduce episodic ozone formation potential can include the reformulation of the remaining solvents.
25. With respect to the industrial use of solvents, three approaches can in principle be used: a product-oriented approach which, for instance, leads to a reformulation of the product (paint, degreasing products, etc.); process-oriented changes; and add-on control technologies. For some industrial uses of solvents only a product-oriented approach is available (in the case of painting constructions, painting buildings, the industrial use of cleaning products, etc.). In all other cases, the product-oriented approach deserves priority, inter alia, because of the positive spin-off effects on the solvent emission of the manufacturing industry. Furthermore, the environmental impact of emissions can be reduced by combining best available technology with product reformulation to replace solvents by less harmful alternatives. According to a combined approach of this kind, the maximum emission reduction potential of up to 60 per cent could lead to an improvement in environmental performance that is significantly higher.
26. There is rapid ongoing development towards low-solvent or solvent-free paints, which are among the most cost-effective solutions. For many plants, a combination of low-solvent and adsorption/incineration techniques are chosen. VOC-emission control for large-scale, industrial painting (e.g. of cars, domestic appliances) could be implemented relatively quickly. Emissions have been reduced as far as 60 g/m2 in several countries. The technical possibility of reducing emissions from new plants to below 20 g/m2 has been recognized by several countries.
27. For the degreasing of metal surfaces, alternative solutions are water-based treatment or closed machines with activated carbon for recovery, with low emissions.
28. For the different printing techniques, several methods to reduce VOC emissions are employed. These mainly involve the changing of inks, changes within the printing process using other printing methods, and gas cleaning techniques. Waterborne ink instead of solvent-based ink is used for flexographic printing on paper and is under development for printing on plastic. Waterborne inks for screen and rotogravure printing are available for
some applications. The use of electron beam cured ink in offset eliminates VOCs and is used in the package printing industry. For some printing methods, UV-cured inks are available. Best available technology for publication rotogravure is the gas cleaning technique using carbon adsorbers. In packaging, the rotogravure recovery of solvent by adsorption (zeolites, active carbon) is practised, but incineration and absorption are also used. For heatset, the web-offset thermal or catalytic incineration of exhaust gases is used. The incineration equipment often includes a unit for heat recovery.
29. For dry-cleaning, the best available technology consists of closed machines and treatment of the exhaust ventilation air by activated carbon filters.
B. Petroleum industry
30. The petroleum industry is one of the major contributors to VOC emissions from stationary sources. Emissions are from both refineries and distribution (including transportation and filling-stations). The following comments refer to table 3; the measures mentioned also include best available technology.
31. Refinery process emissions arise from fuel combustion, flaring of hydrocarbons, vacuum- system discharges and fugitive emissions from process units, such as flanges and connectors, opened lines and sampling systems. Other major VOC emissions within refineries and related activities result from storage, waste-water treatment processes, loading/discharging facilities such as harbours, truck- and railway-racks, pipeline terminals, and periodic operations such as shut-downs, servicing and start-ups (process-unit turnarounds).
32. Process-unit turnaround emissions may be controlled by venting vessel vapours to vapour recovery systems or controlled flaring.
33. Vacuum-system discharges may be controlled by condensation or by piping to boilers or heaters.
34. Fugitive emissions from process equipment in gas/vapour or light liquid service (e.g. automatic control valves, manual valves, pressure relief devices, sampling systems, pumps, compressors, flanges and connectors) can be reduced or prevented by regularly performing leak detection, repair programmes and preventive maintenance. Equipment with substantial leaks (e.g. valves, gaskets, seals, pumps, etc.) can be replaced by equipment that is more leakproof. For example, manual and automatic control valves can be changed for corresponding valves with bellow gaskets. Pumps in gas/vapour and light liquid service can be fitted with dual mechanical seals with controlled degassing vents. Compressors can be equipped with seals with a barrier fluid system that prevents leakage of the process fluid to the atmosphere, and leakage from compressors seals directed to the flares.
35. Pressure relief valves for media that may contain VOCs can be connected to a gas- collecting system and the gases collected burnt in process furnaces or flares.
36. VOC emissions from the storage of crude oil and products can be reduced by equipping fixed-roof tanks with internal floating roofs or by equipping floating-roof tanks with secondary seals.
37. VOC emissions from the storage of petrol and other light liquid components can be reduced by several means. Fixed-roof tanks can be equipped with internal floating roofs with primary and secondary seals or connected to a closed vent system and an effective control device, e.g. vapour recovery, flaring or combustion in process heaters. External floating-roof tanks with primary seals can be equipped with secondary seals, and/or supplemented with tight, fixed roofs, with pressure relief valves which can be connected to the flare.
38. VOC emissions in connection with waste-water handling and treatment can be reduced by several means. Water-seal controls can be installed, as can junction boxes, equipped with tight-fitting covers, in drain systems. Sewer lines can be covered. Alternatively, the drain system can be completely closed to the atmosphere. Oil-water separators, including separation tanks, skimmers, weirs, grit chambers, sludge hoppers and slop-oil facilities, can be equipped with fixed roofs and closed vent systems that direct vapours to a control device, designed either for the recovery or destruction of the VOC vapours. Alternatively, oil-water separators can be equipped with floating roofs with primary and secondary seals. The effective reduction of VOC emissions from waste-water treatment plants can be achieved by draining oil from process equipment to the slop-oil system, thus minimizing the oil-flow into the waste-water treatment plant. The temperature of incoming water can also be controlled in order to lower emissions to the atmosphere.
39. The petrol storage and distribution sector has a high reduction potential. Emission control covering the loading of petrol at the refinery (via intermediate terminals) up to its discharge at petrol service stations is defined as Stage I; control of emissions from the refuelling of cars at service stations is defined as Stage II (see para. 33 of annex III on Control measures for emissions of volatile organic compounds (VOCs) from on-road motor vehicles).
40. Stage I control consists of vapour balancing and vapour collection at the loading of petrol, and recovering the vapour in recovery units. Furthermore, vapour collected at service stations from the discharge of petrol from trucks can be returned and recovered in vapour recovery units.
41. Stage II control consists of vapour balancing between the vehicle fuel tank and the service station’s underground storage tank.
42. Stage II together with Stage I is the best available technology for reducing evaporative emissions during petrol distribution. A complementary means of reducing VOC emissions from fuel storage and handling is to reduce fuel volatility.
43. The overall reduction potential in the petroleum industry sector is up to 80 per cent. This maximum could be reached only where the current level of emission control is low.
C. Organic chemical industry
44. The chemical industry also makes a considerable contribution to VOC emissions from stationary sources. The emissions are of different characters with a wide range of pollutants, because of the variety of products and production processes. Process emissions can be divided into the following major subcategories: reactor-process emissions, air-oxidation emissions and
distillation, and other separation processes. Other significant emission sources are from leaks, storage and product transfer (loading/unloading).
45. For new plants, process modifications and/or new processes often reduce emissions considerably. So-called NNadd-on” or NNend-of-pipe” techniques such as adsorption, absorption, thermal and catalytic incineration in many cases represent alternative or complementary technologies. To reduce evaporation losses from storage tanks and emissions from loading and unloading facilities, the control measures recommended for the petroleum industry (table 3) can be applied. Control measures including best available technologies and their process-related reduction efficiencies are given in table 4.
46. The feasible overall reduction potential in the organic chemical industry is up to 70 per cent, depending on the industry mix and the extent to which control technologies and practices are in place.
D. Stationary combustion
47. Optimal VOC-emission reduction from stationary combustion depends on the efficient use of fuel at the national level (table 5). It is also important to ensure the effective combustion of fuel by the use of good operational procedures, efficient combustion appliances and advanced combustion-management systems.
48. For small systems in particular, there is still a considerable reduction potential, especially in the burning of solid fuels. VOC reduction in general is achievable by the replacement of old stoves/boilers and/or fuel-switching to gas. The replacement of single room stoves by central heating systems and/or the replacement of individual heating systems in general reduces pollution; however, overall energy efficiency has to be taken into account. Fuel-switching to gas is a very effective control measure, provided the distribution system is leakproof.
49. For most countries, the VOC-reduction potential for power plants is negligible. On account of the uncertain replacement/fuel-switch involved, no figures can be given regarding the overall reduction potential and the related costs.
E. Food industry
50. The food industry sector covers a wide range of VOC-emitting processes from large and small plants (table 6). The major sources of VOC emissions are:
(a) Production of alcoholic beverages;
(c) Vegetable oil extraction using mineral oils;
Alcohol is the principal VOC from (a) and (b). Aliphatic hydrocarbons are the principal VOC from (c).
51. Other potential sources include:
(a) Sugar industry and sugar use;
(b) Coffee and nut roasting;
(c) Frying (chipped potatoes, crisps, etc.);
(d) Fish meal processing;
(e) Preparation of cooked meats, etc.
52. VOC emissions are typically odorous, of low concentration with high volume flow and water content. For this reason, the use of biofilters has been used as an abatement technique. Conventional techniques such as absorption, adsorption, thermal and catalytic incineration have also been used. The principal advantage of biofilters is their low operational cost compared with other techniques. Nevertheless, periodic maintenance is required.
53. It may be feasible for larger fermentation plants and bakeries to recover alcohol by condensation.
54. Aliphatic hydrocarbon emissions from oil extraction are minimized by using closed cycles and good housekeeping to prevent losses from valves and seals, etc. Different oil seeds require different volumes of mineral oil for extraction. Olive oil can be extracted mechanically, in which case no mineral oil is necessary.
55. The technologically feasible overall reduction potential in the food industry is estimated to be up to 35 per cent.
F. Iron and steel industry (including ferro-alloys,casting, etc.)
56. In the iron and steel industry, VOC emissions may be from a variety of sources:
(a) Processing of input materials (cokeries; agglomeration plants: sintering, pelletizing, briquetting; scrap-handling);
(b) Metallurgical reactors (submerged arc furnaces; electric arc furnaces; converters, especially if using scrap; (open) cupolas; blast furnaces);
(c) Product handling (casting; reheating furnaces; and rolling mills).
57. Reducing the carbon carrier in raw materials (e.g. on sintering belts) reduces the potential of VOC emissions.
58. In the case of open metallurgical reactors, VOC emissions may occur especially from contaminated scrap and under pyrolytic conditions. Special attention has to be paid to the collection of gases from charging and tapping operations, in order to minimize fugitive VOC emissions.
59. Special attention has to be paid to scrap which is contaminated by oil, grease, paint, etc., and to the separation of fluff (non-metallic parts) from metallic scrap.
60. The processing of products usually entails fugitive emissions. In the case of casting, emissions of pyrolysis gases occur, chiefly from organically bonded sands. These emissions can be reduced by choosing low-emission bonding resins and/or minimizing the quantity of binders. Biofilters have been tested on such flue gases. Oil mist in the air from rolling mills can be reduced to low levels by filtration.
61. Coking plants are an important VOC emission source. Emissions arise from: coke oven gas leakage, the loss of VOCs normally diverted to an associated distillation plant, and from the combustion of coke oven gas and other fuel. VOC emissions are reduced mainly by the following measures: improved sealing between oven doors and frames and between charging holes and covers; maintaining suction from ovens even during charging; dry quenching either by direct cooling with inert gases or by indirect cooling with water; pushing directly into the dry quenching unit; and efficient hooding during pushing operations.
G. Handling and treatment of waste
62. Concerning municipal solid waste control, the primary objectives are to reduce the amount of waste produced and to reduce the amount to be treated. In addition, the waste treatment should be optimized from an environmental point of view.
63. If landfill processes are used, VOC-emission control measures for the treatment of municipal waste should be linked to an efficient collection of the gases (mostly methane).
64. These emissions can be destroyed (incineration). Another option is the purification of the gas (bio-oxidation, absorption, activated carbon, adsorption) leading to use of the gas for energy production.
65. The landfill of industrial waste containing VOCs leads to VOC emissions. This point has to be taken into account in the definition of waste-management policies.
66. The overall reduction potential is estimated to be 30 per cent, though this figure includes methane.
67. The principal sources of VOC emissions from agriculture are:
(a) Burning of agricultural waste, particularly straw and stubble;
(b) Use of organic solvents in pesticide formulations;
(c) Anaerobic degradation of animal feeds and wastes.
68. VOC emissions are reduced by:
(a) Controlled disposal of straw as opposed to the common practice of open-field burning;
(b) Minimal use of pesticides with high organic solvent contents, and/or the use of emulsions and water-based formulations;
(c) Composting of waste, combining manure with straw, etc;
(d) Abatement of exhaust gases from animal houses, manure drying plant, etc., by use of biofilters, adsorption, etc.
69. In addition, alterations of feed reduce emissions of gas from animals, and the recovery of gases for use as fuel is a possibility.
70. It is not currently possible to estimate the reduction potential of VOC emissions from agriculture.
71. In circumstances in which abatement by control techniques is not appropriate, the sole means of reducing VOC emissions is by altering the composition of products used. The main sectors and products concerned are: adhesives used in households, light industry, shops and offices; paints for use in households; household cleaning and personal care products; office products such as correcting fluids and car maintenance products. In any other situation in which products like those mentioned above are used (e.g. painting, light industry), alterations in product composition are highly preferable.
72. Measures aimed at reducing VOC emissions from such products are:
(a) Product substitution;